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Beilstein J. Org. Chem. 2010, 6, 1188–1198, doi:10.3762/bjoc.6.136
Graphical Abstract
Figure 1: Ru-based metathesis catalysts.
Scheme 1: RCM of an allyl ether catalyzed by catalyst H.
Figure 2: Solvent screening for the RCM of 1 catalyzed by H (standardized conditions as denoted in Scheme 1).
Figure 3: Comparison of catalysts D, E and H in toluene and acetic acid (standardized conditions as denoted i...
Figure 4: Conversion vs catalyst loading for the RCM of 1 in acetic acid (standardized conditions as denoted ...
Scheme 2: Catalyst screening for RCM of acrylate 3a.
Figure 5: Acrylates 3 and their RCM products 4.
Scheme 3: Ring closing enyne metathesis reactions.
Scheme 4: Cross metathesis reactions with allylic alcohol 8.